Q16 / 57 · KVPY 2019 (SA) · Chemistry
For a spontaneous process,
- Aenthalpy change of the system must be negative
- Bentropy change of the system must be positive
- Centropy change of the surrounding must be positive
- Correct answerDentropy change of the system plus surrounding must be positive
Solution
For a spontaneous process in an isolated system, the change in entropy is positive, i.e, .
However, if a system is not isolated, the entropy change of both the system and surroundings are to be taken into account because system and surroundings together constitute the isolated system thus, the total entropy change is sum of the change in entropy of the system and the change in entropy of the surroundings
i.e., for a spontenceus process, must be positive, i.e., is also termed as
Hence, the correct answer is option: 'D'.