Q16 / 57 · KVPY 2019 (SA) · Chemistry

For a spontaneous process,
 

  • A
    enthalpy change of the system must be negative
     
  • B
    entropy change of the system must be positive
     
  • C
    entropy change of the surrounding must be positive
     
  • Correct answer
    D
    entropy change of the system plus surrounding must be positive

Solution

 For a spontaneous process in an isolated system, the change in entropy is positive, i.e, ΔS>O.

However, if a system is not isolated, the entropy change of both the system and surroundings are to be taken into account because system and surroundings together constitute the isolated system thus, the total entropy change ΔStotal is sum of the change in entropy of the system ΔSsystem  and the change in entropy of the surroundings ΔSpurroundings 
i.e., ΔStotal =ΔSsystem +ΔSSurrounding  for a spontenceus process, ΔStotal  must be positive, i.e., ΔStotal  is also termed as ΔSuniverse"  

Hence, the correct answer is option: 'D'.

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