Q6 / 90 · JEE Main 2024 (09 Apr Shift 2) · Chemistry

For a sparingly soluble salt \(\mathrm{AB}_2\), the equilibrium concentrations of \(\mathrm{A}^{2+}\) ions and \(B^{-}\)ions are \(1.2 \times 10^{-4} \mathrm{M}\) and \(0.24 \times 10^{-3} \mathrm{M}\), respectively. The solubility product of \(\mathrm{AB}_2\) is :

  • Correct answer
    A
    \(6.91 \times 10^{-12}\)
  • B
    \(0.276 \times 10^{-12}\)
  • C
    \(27.65 \times 10^{-12}\)
  • D
    \(0.069 \times 10^{-12}\)

Solution

$\begin{aligned} & \mathrm{AB}_{2(\mathrm{~s})} \rightleftharpoons \mathrm{A}_{(\mathrm{aq})}^{+2}+2 \mathrm{~B}_{(\mathrm{aq})}^{-} \\ & \mathrm{K}_{\mathrm{sp}}=\left[\mathrm{A}^{+2}\right]\left[\mathrm{B}^{-}\right]^2 \\ &=1.2 \times 10^{-4} \times\left(2.4 \times 10^{-4}\right)^2 \\ &=6.91 \times 10^{-12} \mathrm{M}^3\end{aligned}$

Hence, the correct answer is option: 'A'.

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