Q50 / 170 · Manipal (MET) 2020 · Chemistry

$\mathrm{K}_2\left[\mathrm{Hgl}_4\right]$ detects the following ion

  • A
    $\mathrm{Cl}^{-}$
  • B
    $\mathrm{NO}_2^{-}$
  • C
    $\mathrm{NO}_3^{-}$
  • Correct answer
    D
    $\mathrm{NH}_4^{+}$

Solution

Analysis of $\mathrm{NH}_4^{+}$cation Take small amount of salt in the test tube and add NaOH and heat. Add Nessler's reagent $\left[\mathrm{K}_2 \mathrm{H}_3 \mathrm{I}_4\right]$ to the solution, brown ppt is obtained. It confirmed $\mathrm{NH}_4^{+}$ion. Figure

Hence, the correct answer is option: 'D'.

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