Q74 / 180 · AIIMS 2019 (26 May) · Chemistry
Correct order for reaction with alcoholic $\mathrm{KOH}$ is


- Ai $>$ ii $>$ iii $>$ iv
- Correct answerBi $>$ iii $>$ ii $>$ iv
- Civ $>$ ii $>$ iii $>\mathrm{i}$
- Di $>$ iv $>$ ii $>$ iii
Solution
$-\mathrm{Br}$ is good leaving group than $-\mathrm{Cl}$ due to low bond dissociation energy of $\mathrm{C}-\mathrm{Br}$ bond. $2^{\circ}$ carbocation is more stable than $1^{\circ}$ carbocation. More substituted alkene is more stable (Saytzeff's rule).


Hence, the correct answer is option: 'B'.