Q38 / 160 · TS EAMCET 2023 (12 May Shift 1) · Chemistry

Consider the following reaction sequence Figure
The correct statements about $\mathrm{Z}$ are I. It gives yellow precipitate with $\mathrm{I}_2$ and $\mathrm{NaOH}$ solution II. It undergoes disproportionation reaction in the presence of concentrated $\mathrm{NaOH}$ solution III. It undergoes wolff-Kishner reduction IV. It forms red precipitate with Fehling's reagent

  • A
    I & II only
  • B
    II & III only
  • C
    I & IV only
  • Correct answer
    D
    I & III only

Solution

Figure
Since ' $\mathrm{Z}$ ' is a methyl ketone, it gives positive iodoform test and gives a yellow precipitate with $\mathrm{I}_2$ and $\mathrm{NaOH}$. Aldehydes and ketones undergo walff-kishner reduction to give the corresponding hydrocarbon. Thus, I and III are correct.,

Hence, the correct answer is option: 'D'.

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