Q38 / 160 · TS EAMCET 2023 (12 May Shift 1) · Chemistry
Consider the following reaction sequence

The correct statements about $\mathrm{Z}$ are
I. It gives yellow precipitate with $\mathrm{I}_2$ and $\mathrm{NaOH}$ solution
II. It undergoes disproportionation reaction in the presence of concentrated $\mathrm{NaOH}$ solution
III. It undergoes wolff-Kishner reduction
IV. It forms red precipitate with Fehling's reagent

The correct statements about $\mathrm{Z}$ are I. It gives yellow precipitate with $\mathrm{I}_2$ and $\mathrm{NaOH}$ solution II. It undergoes disproportionation reaction in the presence of concentrated $\mathrm{NaOH}$ solution III. It undergoes wolff-Kishner reduction IV. It forms red precipitate with Fehling's reagent
- AI & II only
- BII & III only
- CI & IV only
- Correct answerDI & III only
Solution

Since ' $\mathrm{Z}$ ' is a methyl ketone, it gives positive iodoform test and gives a yellow precipitate with $\mathrm{I}_2$ and $\mathrm{NaOH}$. Aldehydes and ketones undergo walff-kishner reduction to give the corresponding hydrocarbon. Thus, I and III are correct.,
Hence, the correct answer is option: 'D'.