Q13 / 90 · JEE Main 2010 · Chemistry

Consider the following bromides : Figure
The correct order of $\mathrm{S}_{\mathrm{N}} 1$ reactivity is

  • Correct answer
    A
    $B>C>A$
  • B
    $B>A>C$
  • C
    $C>B>A$
  • D
    $A>B>C$

Solution

$\mathrm{S}_{\mathrm{N}} 1$ proceeds via carbocation intermediate, the most stable one forming the product faster. Hence reactivity order for $\mathrm{A}, \mathrm{B}, \mathrm{C}$ depends on stability of carbocation created. Figure

Hence, the correct answer is option: 'A'.

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