Q21 / 59 · NEST (NISER) 2018 · Chemistry
Complexes $\left[\mathrm{CoX}_6\right]^{3-},\left[\mathrm{CoY}_6\right]^{3+}$ and $\left[\mathrm{CoZ}_6\right]^{3-}$ absorb at 700,475 and 310 nm , respectively. The ligands $\mathrm{X}, \mathrm{Y}$ and Z most likely are, respectively,
- Correct answerA$\mathrm{F}^{-}, \mathrm{NH}_3, \mathrm{CN}^{-}$
- B$\mathrm{CN}^{-}, \mathrm{H}_2 \mathrm{O}, \mathrm{Cl}^{-}$
- C$\mathrm{Br}^{-}, \mathrm{NH}_3, \mathrm{NCS}^{-}$
- D$\mathrm{I}^{-}, \mathrm{H}_2 \mathrm{O}, \mathrm{OH}^{-}$
Hence, the correct answer is option: 'A'.