Q18 / 180 · COMEDK 2024 (Morning Shift) · Chemistry
Choose the incorrect statement from the following
- A$\mathrm{Cu}$ (I) compounds in aqueous medium undergo disproportionation reaction
- B$\mathrm{MoO}_3$ and $\mathrm{WO}_3$ are not as strong oxidants as $\mathrm{CrO}_3$
- Correct answerCThe ability of Fluorine to stabilise the higher oxidation states of transition metals exceeds that of Oxygen
- D$\mathrm{Cr}^{2+}$ is a stronger reducing agent than $\mathrm{Fe}^{2+}$
Solution
(1) Correct: $Cu^+$ is unstable in aqueous medium due to the much higher hydration energy of $Cu^{2+}$. It undergoes disproportionation: $2Cu^+(aq) \to Cu^{2+}(aq) + Cu(s)$.
(2) Correct: Oxidising power decreases down Group 6. $CrO_3$ is a strong oxidant while $MoO_3$ and $WO_3$ are much weaker.
(3) Incorrect: Oxygen can stabilise higher oxidation states through multiple bonding (e.g., in oxoanions like $MnO_4^-$, $CrO_4^{2-}$). The ability of oxygen to stabilise higher oxidation states is superior to that of fluorine in many cases. So the statement that fluorine exceeds oxygen is incorrect.
(4) Correct: $Cr^{2+}(d^4)$ is oxidised to $Cr^{3+}(d^3$, stable $t_{2g}^3)$. $E°(Cr^{3+}/Cr^{2+}) = -0.41$ V, while $E°(Fe^{3+}/Fe^{2+}) = +0.77$ V. Lower reduction potential means $Cr^{2+}$ is a stronger reducing agent than $Fe^{2+}$.
The incorrect statement is (3).
(2) Correct: Oxidising power decreases down Group 6. $CrO_3$ is a strong oxidant while $MoO_3$ and $WO_3$ are much weaker.
(3) Incorrect: Oxygen can stabilise higher oxidation states through multiple bonding (e.g., in oxoanions like $MnO_4^-$, $CrO_4^{2-}$). The ability of oxygen to stabilise higher oxidation states is superior to that of fluorine in many cases. So the statement that fluorine exceeds oxygen is incorrect.
(4) Correct: $Cr^{2+}(d^4)$ is oxidised to $Cr^{3+}(d^3$, stable $t_{2g}^3)$. $E°(Cr^{3+}/Cr^{2+}) = -0.41$ V, while $E°(Fe^{3+}/Fe^{2+}) = +0.77$ V. Lower reduction potential means $Cr^{2+}$ is a stronger reducing agent than $Fe^{2+}$.
The incorrect statement is (3).
Hence, the correct answer is option: 'C'.