Q3 / 160 · TS EAMCET 2023 (13 May Shift 1) · Chemistry

Choose the correct order of second ionisation enthalpies Carbon, Nitrogen, Oxygen and Fluorine.

  • A
    Carbon $>$ Nitrogen $>$ Oxygen $>$ Fluorine
  • B
    Oxygen $>$ Carbon $>$ Nitrogen $>$ Fluorine
  • C
    Fluorine $>$ Nitrogen $>$ Carbon $>$ Oxygen
  • Correct answer
    D
    Oxygen $>$ Fluorine $>$ Nitrogen $>$ Carbon

Solution

The corresponding electronic configurations for the given species are: $\mathrm{C}: 1 \mathrm{~s}^2 2 \mathrm{~s}^2 2 \mathrm{p}^2, \mathrm{~N}: 1 \mathrm{~s}^2 2 \mathrm{~s}^2 2 \mathrm{p}^3, \mathrm{O}: 1 \mathrm{~s}^2 2 \mathrm{~s}^2 2 \mathrm{p}^4$ F : $1 \mathrm{~s}^2 2 \mathrm{~s}^2 2 \mathrm{p}^5$. Since there are three 2 p-orbitals in the 2 p-subshell, it is evident that the loss of a second electron from the valence shell will be most difficult in oxygen as it would disturb the stable half-filled p-subshell. The removal of second electron will be easiest for carbon as it would give a fully-filled $2 \mathrm{~s}$-subshell. Thus, the order of second ionization energy will be:Oxygen $>$ Fluorine $>$ Nitrogen $>$ Carbon

Hence, the correct answer is option: 'D'.

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