Q17 / 100 · BITSAT 2024 (Memory Based Paper 1) · Chemistry
Choose the correct option for free expansion of an ideal gas under adiabatic condition from the following:
- A$\mathrm{q}=0, \Delta \mathrm{~T} \neq 0, \mathrm{w}=0$
- B$q=0, \Delta T \lt 0, w \neq 0$
- C$\mathrm{q}=\neq 0, \Delta \mathrm{~T}=0, \mathrm{w}=0$
- Correct answerD$\mathrm{q}=0, \Delta \mathrm{~T}=0, \mathrm{w}=0$
Solution
$\Delta U=q+w$
For a adiabatic process,
$\Delta \mathrm{U}=\mathrm{w}=-\mathrm{p}_{\mathrm{ex}} \Delta \mathrm{v}$
For free expansion of ideal gas $\mathrm{p}_0=0$
As $\Delta \mathrm{U}=\mathrm{C} \Delta \mathrm{T}=0$
$\Delta \mathrm{U}=\mathrm{w}=-\mathrm{p}_{\mathrm{ex}} \Delta \mathrm{v}$
For free expansion of ideal gas $\mathrm{p}_0=0$
As $\Delta \mathrm{U}=\mathrm{C} \Delta \mathrm{T}=0$
Hence, the correct answer is option: 'D'.