Q66 / 200 · NEET 2006 · Chemistry
$\mathrm{Al}_2 \mathrm{O}_3$ can be converted to anhydrous $\mathrm{AlCl}_3$ by heating:
- A$\mathrm{Al}_2 \mathrm{O}_3$ with $\mathrm{Cl}_2$ gas
- B$\mathrm{Al}_2 \mathrm{O}_3$ with $\mathrm{HCl}$ gas
- C$\mathrm{Al}_2 \mathrm{O}_3$ with $\mathrm{NaCl}$ in solid state
- Correct answerDA mixture of $\mathrm{Al}_2 \mathrm{O}_3$ and carbon in dry $\mathrm{Cl}_2$ gas
Solution
$\mathrm{Al}_2 \mathrm{O}_3$ may be converted to anhydrous $\mathrm{AlCl}_3$ by heating a mixture of $\mathrm{Al}_2 \mathrm{O}_3$ and carbon in dry chlorine.
$\mathrm{Al}_2 \mathrm{O}_3+3 \mathrm{C}+3 \mathrm{Cl}_2 \rightarrow \underset{\text {(anhydrous } \mathrm{AlCl}_3)}{\mathrm{Al}_2 \mathrm{Cl}_6}$
Hence, the correct answer is option: 'D'.