Q14 / 77 · NTA Abhyas (JEE Main) 2020 · Chemistry · Solid State

Band theory predicts that magnesium is an insulator. However, in practice it acts as a conductor due to

  • A
    presence of filled 3s – orbital
  • B
    overlap of filled 2p and filed 3s- orbital
  • Correct answer
    C
    overlap of filled 3s and empty 3p-orbital
  • D
    presence of unfilled 3p –orbital

Solution

The electronic configuration of Mg is
1s2,2s2,2p6,3s2,3p0
In it 3s – orbital is completely filed and 3p-orbital is empty. There is very small energy difference between 3s and 3p – orbitals. Thus, they overlap and make the Mg a conductor.
Figure
Band model of Mg

Hence, the correct answer is option: 'C'.

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