Q24 / 90 · JEE Main 2021 (22 Jul Shift 1) · Chemistry

Assume a cell with the following reaction Cu(s)+2Ag+1×10-3M→Cu2+(0.250M)+2Ag(s)
Ecell ∘=2.97 V

Ecell  for the above reaction is         V.

(Nearest integer)

[ Given : log2.5=0.3979, T=298 K]

Correct answer: 3

Solution

E=E°-0.0592logCu+2Ag+2
=2.97-0.0592log0.2510-32=2.81 V

Hence, the correct answer is 3.

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