Q53 / 180 · AIIMS 2008 · Chemistry

Assertion : Phenol is more reactive than benzene towards electrophilic substitution reaction. Reason : In the case of phenol, the intermediate carbocation is more resonance stabilised.

  • A
    If both assertion and reason are true and reason is the correct explanation of assertion.
  • B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
  • Correct answer
    C
    If assertion is true but reason is false.
  • D
    If both assertion and reason are false.

Solution

$-\mathrm{OH}$ group shows $+M$ effect and is an activating group, moreover the arenium ion of phenolic substitution is more stable. Figure

Hence, the correct answer is option: 'C'.

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