Q53 / 180 · AIIMS 2008 · Chemistry
Assertion : Phenol is more reactive than benzene towards electrophilic substitution reaction.
Reason : In the case of phenol, the intermediate carbocation is more resonance stabilised.
- AIf both assertion and reason are true and reason is the correct explanation of assertion.
- BIf both assertion and reason are true but reason is not the correct explanation of assertion.
- Correct answerCIf assertion is true but reason is false.
- DIf both assertion and reason are false.
Solution
$-\mathrm{OH}$ group shows $+M$ effect and is an activating group, moreover the arenium ion of phenolic substitution is more stable.


Hence, the correct answer is option: 'C'.