Q64 / 180 · AIIMS 2002 · Chemistry
Assertion : Diamond is a bad conductor.
Reason : Graphite is a good conductor.
- AIf both the assertion and reason are true and reason is a correct explanation of the assertion.
- Correct answerBIf both assertion and reason are true but assertion is not a correct explanation of the assertion.
- CIf the assertion is true but the reason is false.
- DIf both assertion and reason are false.
Solution
In diamond, each carbon atom is in $s p^3$ hybridised state and linked to four other carbon atoms tetraherallyby covalent bonds. Since there is no mobile electron present, diamond is a bad conductor of heat and electricity.
In graphite each carbon atom is in $s p^2$ hybridised state and is linked to three other carbon atoms in a hexagonal planar structure. The $\pi$-electrons are free to move throughout the entire layers, therefore graphite is a good conductor of heat and electricity.
Hence, the correct answer is option: 'B'.