Q64 / 180 · AIIMS 2002 · Chemistry

Assertion : Diamond is a bad conductor. Reason : Graphite is a good conductor.

  • A
    If both the assertion and reason are true and reason is a correct explanation of the assertion.
  • Correct answer
    B
    If both assertion and reason are true but assertion is not a correct explanation of the assertion.
  • C
    If the assertion is true but the reason is false.
  • D
    If both assertion and reason are false.

Solution

In diamond, each carbon atom is in $s p^3$ hybridised state and linked to four other carbon atoms tetraherallyby covalent bonds. Since there is no mobile electron present, diamond is a bad conductor of heat and electricity. In graphite each carbon atom is in $s p^2$ hybridised state and is linked to three other carbon atoms in a hexagonal planar structure. The $\pi$-electrons are free to move throughout the entire layers, therefore graphite is a good conductor of heat and electricity.

Hence, the correct answer is option: 'B'.

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