Q28 / 180 · AIIMS 2018 (26 May) · Chemistry
Assertion : Benzyl amine is less basic than ethyl amine.
Reason : Benzene shows $+I$-effect.
- AIf both assertion and reason are true and reason is the correct explanation of assertion.
- BIf both assertion and reason are true but reason is not the correct explanation of assertion.
- Correct answerCIf assertion is true but reason is false.
- DIf both assertion and reason are false.
Solution
$\mathrm{PhCH}_2 \mathrm{NH}_2$ (Benzyl amine) has $-I$-effect of phenyl group while $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{NH}_2$ has $+I$-effect of ethyl group.
Hence, the correct answer is option: 'C'.