Q51 / 180 · AIIMS 2001 · Chemistry

Assertion : $\mathrm{B}_2 \mathrm{H}_6, \mathrm{Si}_2 \mathrm{H}_6$ are said to have similar structure. Reason : They have same number of $\sigma$ and $\pi$ bonds .

  • A
    If both Assertion and Reason are true and Reason is the correct explanation of Assertion.
  • B
    If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
  • C
    If Assertion is true but Reason is false.
  • Correct answer
    D
    If Assertion is false but Reason is true.

Solution

$\mathrm{B}_2 \mathrm{H}_6$ is an electron deficient compound. $\mathrm{B}_2 \mathrm{H}_6$ contain some unusual bonds which are called as 2 -electron 3 -centre bonds. Figure

Hence, the correct answer is option: 'D'.

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