Q24 / 180 · KCET 2009 · Chemistry

An organic compound $X$ is oxidised by using acidified $\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}$. The product obtained reacts with phenyl hydrazine but does not answer silver mirror test. The possible structure of $X$ is

  • A
    $\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}$
  • B

    Figure
  • Correct answer
    C
    $\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}$
  • D
    $\mathrm{CH}_{3} \mathrm{CHO}$

Solution


Figure
Ketone (ie, acetone) reacts with phenyl hydrazine but does not give silver mirror test.

Hence, the correct answer is option: 'C'.

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