Q33 / 160 · TS EAMCET 2015 · Chemistry

An element in +2 oxidation state has 24 electrons. The atomic number of the element and the number of unpaired electrons in it respectively are

  • A
    24 and 4
  • Correct answer
    B
    26 and 4
  • C
    24 and 2
  • D
    26 and 5

Solution

$$ \begin{aligned} & { }_{26} \mathrm{Fe}=1 s^2, 2 s^2 2 p^6, 3 s^2 3 p^6, 4 s^2, 3 d^6 \\ & { }_{26} \mathrm{Fe} \longrightarrow{ }_{26} \mathrm{Fe}^{2+} \end{aligned} $$ Hence, atomic number of iron $(\mathrm{Fe})$ is 26 and $\mathrm{Fe}^{2+}$ have 4 unpaired electrons in $3 d$-orbital.

Hence, the correct answer is option: 'B'.

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