Q18 / 75 · JEE Main 2025 (7 Apr Shift 1) · Chemistry

An aqueous solution of HCl with pH 1.0 is diluted by adding equal volume of water (ignoring dissociation of water). The pH of HCl solution would
(Given $\log 2=0.30)$

  • A
    reduce to $0.5$
  • Correct answer
    B
    increase to $1.3$
  • C
    remain same
  • D
    increase to $2$

Solution

$\mathrm{HCl}_{(\mathrm{aq})} \mathrm{pH}=1 ;\left[\mathrm{H}^{+}\right]=10^{-1}$
If equal volume of water is added concentration will become half
$\begin{aligned}& {\left[\mathrm{H}^{+}\right]_{\mathrm{sol}}=\frac{10^{-1}}{2}} \\& \mathrm{pH}=1.3\end{aligned}$

Hence, the correct answer is option: 'B'.

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