Q62 / 160 · JIPMER 2014 · Chemistry

Among the following the least thermally stable is

  • A
    $\mathrm{K}_2 \mathrm{CO}_3$
  • B
    $\mathrm{Na}_2 \mathrm{CO}_3$
  • C
    $\mathrm{BaCO}_3$
  • Correct answer
    D
    $\mathrm{Li}_2 \mathrm{CO}_3$

Solution

Thermal stability of carbonates increases on moving down a group. Thus, lithium carbonate, $\mathrm{Li}_2 \mathrm{CO}_3$ is least thermally stable. $\mathrm{Li}_2 \mathrm{CO}_3 \xrightarrow{\Delta} \mathrm{Li}_2 \mathrm{O}+\mathrm{CO}_2$

Hence, the correct answer is option: 'D'.

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