Q141 / 200 · MHT CET - Medical 2026 (23 April Shift 2) · Chemistry

Aldehydes containing at least one $\alpha$-hydrogen atom undergo a reaction in presence of dilute aq. NaOH to form $\beta$-hydroxyl aldehyde. Identify the reaction.

  • A
    Cannizaro reaction
  • Correct answer
    B
    Aldol reaction
  • C
    Reformatsky reaction
  • D
    Wolf-Kishner reaction

Solution

Aldehydes containing at least one $\alpha$-hydrogen atom undergo self-addition in the presence of a dilute base like aqueous NaOH to form $\beta$-hydroxy aldehydes. This reaction is known as the Aldol reaction.

For example, two molecules of ethanal react in the presence of dilute NaOH to form 3-hydroxybutanal (an aldol).

Cannizzaro reaction is given by aldehydes lacking $\alpha$-hydrogen atoms.

Reformatsky reaction involves the reaction of an $\alpha$-halo ester with a carbonyl compound in the presence of zinc.

Wolff-Kishner reaction is the reduction of carbonyl compounds to alkanes using hydrazine and a strong base.

Answer: Aldol reaction

Hence, the correct answer is option: 'B'.

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