Q141 / 200 · MHT CET - Medical 2026 (23 April Shift 2) · Chemistry
Aldehydes containing at least one $\alpha$-hydrogen atom undergo a reaction in presence of dilute aq. NaOH to form $\beta$-hydroxyl aldehyde. Identify the reaction.
- ACannizaro reaction
- Correct answerBAldol reaction
- CReformatsky reaction
- DWolf-Kishner reaction
Solution
Aldehydes containing at least one $\alpha$-hydrogen atom undergo self-addition in the presence of a dilute base like aqueous NaOH to form $\beta$-hydroxy aldehydes. This reaction is known as the Aldol reaction.
For example, two molecules of ethanal react in the presence of dilute NaOH to form 3-hydroxybutanal (an aldol).
Cannizzaro reaction is given by aldehydes lacking $\alpha$-hydrogen atoms.
Reformatsky reaction involves the reaction of an $\alpha$-halo ester with a carbonyl compound in the presence of zinc.
Wolff-Kishner reaction is the reduction of carbonyl compounds to alkanes using hydrazine and a strong base.
Answer: Aldol reaction
For example, two molecules of ethanal react in the presence of dilute NaOH to form 3-hydroxybutanal (an aldol).
Cannizzaro reaction is given by aldehydes lacking $\alpha$-hydrogen atoms.
Reformatsky reaction involves the reaction of an $\alpha$-halo ester with a carbonyl compound in the presence of zinc.
Wolff-Kishner reaction is the reduction of carbonyl compounds to alkanes using hydrazine and a strong base.
Answer: Aldol reaction
Hence, the correct answer is option: 'B'.