Q56 / 180 · COMEDK 2024 (Morning Shift) · Chemistry

Figure Above figure represents Vapour pressure versus Temperature graphs of 2 pure volatile liquids and a solution formed by the 2 liquids. (i) Which curve represents the solution? (ii) Which curve represents the liquid with the strongest intermolecular forces of attraction?

  • A
    (i) B (ii) A
  • B
    (i) A (ii) C
  • C
    (i) C (ii) A
  • Correct answer
    D
    (i) B (ii) C

Solution

The vapour pressure of a solution containing two volatile liquids is always intermediate between the vapour pressures of the two pure components at a given temperature. In the graph, curve A represents the liquid with the highest vapour pressure (weakest intermolecular forces), curve C represents the liquid with the lowest vapour pressure (strongest intermolecular forces), and curve B represents the solution formed by these two liquids.

Therefore, (i) curve B represents the solution, and (ii) curve C represents the liquid with the strongest intermolecular forces of attraction.

Answer: (i) B (ii) C

Hence, the correct answer is option: 'D'.

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