Q16 / 51 · JEE Advanced 2023 (Paper 2) · Chemistry
A trinitro compound, -tris-(-nitrophenyl) benzene, on complete reaction with an excess of gives a major product, which on treatment with an excess of at provides as the product. , upon treatment with excess of at room temperature, gives the product . Bromination of in aqueous medium furnishes the product . The compound upon treatment with an excess of phenol under basic conditions gives the product . The molar mass difference between compounds and is and between compounds and is .
The number of heteroatoms present in one molecule of is [Use: Molar mass (in g mol-1): Atoms other than and are considered as heteroatoms]
The number of heteroatoms present in one molecule of is [Use: Molar mass (in g mol-1): Atoms other than and are considered as heteroatoms]
Correct answer: 9
Solution
Nitrobenzene part converts to aniline part using . Aniline forms diazonium salt with nitrous acid and hydrogen chloride. Diazonium salt forms phenol with warm water.Phenol forms poly substituted bromo compound with bromine water.
The hetero atoms present the product are 6 bromine atoms and 3 oxygen atoms. Number of Hetero atoms in is .
Hence, the correct answer is 9.


