Q10 / 91 · KVPY 2020 (SB/SX) · Chemistry

A mixture of toluene and benzene forms a nearly ideal solution. Assume PB° and PT° to be the vapor pressures of pure benzene and toluene, respectively. The slope of the line obtained by plotting the total vapor pressure to the mole fraction of benzene is:-

  • Correct answer
    A
    PB°-PT°
  • B
    PT°-PB°
  • C
    PB°+PT°
  • D
    PB°+PT°/2

Solution

Ptotal =χBPB0+χTPT0=χBPB0+1-χBPT0
Comparing it with y=mx+c
Ptotal y=χBxPB0-PT0⏟m+PT0⏟c

Hence, the correct answer is option: 'A'.

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