Q17 / 199 · NTA Abhyas (NEET) 2020 · Chemistry · Electrochemistry

A fuel cell involves combustion of the butane at 1 atm and 298 K,
C4H10(g)+132O2(g)→4CO2(g)+5H2O(l)
ΔG°=-2746 kJ/mol
What is E° of a cell?

  • A
    +4.74 V
  • B
    +0.547 V
  • Correct answer
    C
    +1.09 V
  • D
    +4.37 V

Solution

In the reaction
C4H10g-10+10+132O2g→4CO2g+4-4+5H2Ol
Change in oxidation number of carbon =+16-(-10)=+26
So number of electrons involved in cell process will be 26.
E°=-ΔG°nF=(-2746)×100026×96500
=+1.09 V

Hence, the correct answer is option: 'C'.

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