Q45 / 51 · JEE Advanced 2023 (Paper 1) · Physics

A closed container contains a homogeneous mixture of two moles of an ideal monatomic gas γ=53 and one mole of an ideal diatomic gas γ=75. Here, γ is the ratio of the specific heats at constant pressure and constant volume of an ideal gas. The gas mixture does a work of 66 Joule when heated at constant pressure. The change in its internal energy is _____ Joule.

Correct answer: 121

Solution

Change in internal energy for the mixture can be written as,∆U=n1Cv1∆T+n2Cv2∆T

=n1Cv1+n2Cv2∆T     ...i

For isobaric process, work done =P∆V

=n1+n2R∆T      ...ii

Divide i by ii, we get

∆UW=n1Cv1+n2Cv2∆Tn1+n2R∆T

⇒∆U=WRn1Cv1+n2Cv2n1+n2

=66R2×3R2+1×5R22+1

=121 J

Hence, the correct answer is 121.

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