Q42 / 160 · NTA Abhyas (NEET) 2020 · Chemistry · Solutions

0.85% aqueous solution of NaNO3 is apparently 90% dissociated. The osmotic pressure of solution at 300 K is

  • Correct answer
    A
    4.674 atm
  • B
    46.74 atm
  • C
    2.46 atm
  • D
    4.674 mm Hg

Solution

M=W×1000mol.wt.×V
Molarity =1000cm3×0.85g100cm3×85gmol-1=0.1molL-1
NaNO3→Na++NO3-
So i=1-α+α-α1
=1+α=1+0.90=1.90
π=iCRT=1.90×0.1×0.082×300
=4.674 atm.

Hence, the correct answer is option: 'A'.

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