Q30 / 90 · JEE Main 2022 (28 Jun Shift 2) · Chemistry

0.01MKMnO4 solution was added to 20.0 mL of 0.05M Mohr 's salt solution through a burette. The initial reading of 50 mL burette is zero. The volume of KMnO4 solution left in the burette after the end point is....... mL. (nearest integer)

Correct answer: 30

Solution

Fe2++MnO4-⟶Fe3++Mn2+

vf=1  vf=5

vf=Valency factor

Milli equivalents of mohr's salt = milli equivalents of KMnO4

1×0.05×20=5 0.01×Vml

Vml =20ml

Volume of KMnO4 left = 50-20=30ml

Hence, the correct answer is 30.

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